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Interactive Demos
 92

U

Uranium

Uranium General Information
 Categories
  • Class: AcTinides
  • Period: 7
  • IUPAC group: 3
  • Traditional: IIIa
History
  • Discovered in: 1789 by Klaproth
  • Origin of name: The planet Uranus
  • Historical or alternate name:
Common natural occurrences

Pitchblende, uraninite, carnotite, autunite, uranophane, & tobernite

Description

Silvery, ductile, malleable metal. Resists alkalis; tarnishes in air; attacked by steam and acids.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 0.018 ppm
  • Sea water: 0.003 ppm
  • Metallic meteorite: 0.0081 ppm
  • ConTinental crust: 0.91 ppm
  • Solar photosphere: <0.60 log of abundance
  • Oceanic crust: 0.010 ppm
  • Solar system: 0.009 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Poison. Radiotoxic. Compounds highly toxic. Cumulative effects. Flammable solid. Reacts violently with air and water..

   Human daily limits
  • Lower:
  • Upper:0.01

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Uranium Physical Properties

 Transitional Data

  • State: Solid
  • Density: 19.05 g/cm3

 Molar enthalpy

  • Atomization: 535.43 kJ mol-1
  • Fusion: 15.5 kJ mol-1
  • Vaporization: 417.1 kJ mol-1

 Transition points

  • MelTing point: 1405.5 K
  • Boiling point: 4091.0 K
  • Critical temperature: 12500.0 K

 Molar properties

  • Atomic weight: 238.0289 g/mole
  • Molar volume: 12.572 cm3 mol-1

 Crystal structure sequence

orthorhombic <935 K < complex-tetragonal < 1045 K < body-centered-cubic < melTing point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 50.21
    • Heat Capacity 27.665
  • State: gas
    • Enthalpy 535.6
    • Gibbs function 491.2
    • Entropy 199.77
    • Heat Capacity 23.694

 Miscellaneous physical

  • Electrical resistivity: 30.0 µ-ohms/cm
  • Debye temperature: 207.0 K
  • Thermal conductivity: 27.6 W / m / K
  • Coefficient of linear expansion: 14.0Coef. per K
  • Mass magnetic susceptibility: 2.16e-8
  • X-ray diffraction mass absorption coefficients:
    • CuK: 352 (µ/p)/cm2 g-1
    • MoK: 153 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Uranium Chemical Properties

 Chemical basics:

  • Oxidation states: +3 +4 +5 +6
  • Molecular wt: 238.0289 g/mole

 Radii

  • Covalent: pm
  • Atomic: 156.0 pm
  • Van der Waals: pm

 Ions:

  • ion: +3 pm 102.5
  • ion: +4 pm 89.0
  • ion: +5 pm 76.0
  • ion: +6 pm 73.0

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 1.80
  • Clementi:
  • Froese-Fischer:

 Electronegativity

  • Pauling: 1.4
  • Allred-Rochow: 1.22

 Standard reactions

oxidation =>
UO2+2 + 4H+ + 2e- =>
UO2+2 + e- =>
U+4 + e- =>
U+4 + 4e- =>
U+3 + 3e- =>

reduction
U+4 + 2H2O
UO2+
U+3
U
U
potential
0.334
0.062
-0.61
-1.40
-1.8

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Uranium Nuclear Properties

Isotopes
Number of isotopes:
  • Known 15
  • Listed 8
Isotope range:
  • Known 227 - 240
  • Listed 230 - 238
Nuclide 230
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 20.800 days
    • Decay mode: alpha,
    • Source:
  • Notes
Nuclide 232
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 70.000 years
    • Decay mode: alpha, S.F.
    • Source:
  • Notes
Nuclide 233
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 5/2
  • Radioisotopes:
    • Half-life: 0.159 E6 years
    • Decay mode: alpha,
    • Source:
  • Notes
Nuclide 234
  • % Occ.:Natural 0.0055%
  • Mossbauer NRA: 6.97
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 0.248 E6 years
    • Decay mode: alpha, S.F.
    • Source:
  • Notes
Nuclide 235
  • % Occ.:Natural 0.7200%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 7/2
  • Radioisotopes:
    • Half-life: 0.713 E9 years
    • Decay mode: alpha, S.F.
    • Source:
  • Notes date
Nuclide 236
  • % Occ.:Natural
  • Mossbauer NRA: 7.24
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 23.420 E6 years
    • Decay mode: alpha, S.F.
    • Source:
  • Notes
Nuclide 237
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 6.750 days
    • Decay mode: Beta-
    • Source:
  • Notes
Nuclide 238
  • % Occ.:Natural 99.2745%
  • Mossbauer NRA: 7.16 *
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 4.490 E9 years
    • Decay mode: alpha, S.F.
    • Source:
  • Notes date
Thermal neutron capture
  • Isotope Cross-section 7.60±0.07 barns
Nuclear magnetic resonance
Nuclide: 235
  • Absolute sensitivity: 8.71e-7 1H=1.0
  • Relative sensitivity: 1.21e-4 1H=1.0
  • Receptivity: 5.4e-3 13C=1.0
  • Magnetogyric ratio: -0.4926e7 rad / T / s
  • Quadropole moment: 4.55e-28 m2
  • Frequency: 1.790 MHz
  • Reference: UF6

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Uranium Energy Properties

Electrons

  • Ground state electron configuration: [Rn] 5f3 6d1 7s2
  • Electron affinity: kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 3566.60
  • Relative intensity 95
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 180 NA
  • Notes:
 Wave length 3584.88
  • Relative intensity 130
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 120 NA
  • Notes:
 Wave length 3670.07
  • Relative intensity 160
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml) 100
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 4241.67
  • Relative intensity 75
  • Detection limits
    • Arc (ug/g) 100
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 5915.40
  • Relative intensity 20
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 10 OAnz
    • Atomic absorption (ug/ml)
  • Notes:

 Ionization energies

Ionization level
U -> U+
U+ -> U+2
Ionization potential
584
1420

 Atomic energy levels

Orbital
ns
(n-1)d
(n-2)f
Energy
0.7695
0.9796
2.5788

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

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