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 70

Yb

YtTErbium

YtTErbium General Information
 Categories
  • Class: Heavy Lanthinides
  • Period: 6
  • IUPAC group: 3
  • Traditional: IIIa
History
  • Discovered in: 1878 by de Marignac
  • Origin of name: Ytterby, village in Sweden
  • Historical or alternate name:
Common natural occurrences

Monazite

Description

Soft, Silvery white metal. Oxidizes slowly in air. Reacts with water.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 0.372 ppm
  • Sea water: 2e-7 ppm
  • Metallic meteorite: 0.166 ppm
  • ConTinental crust: 2.2 ppm
  • Solar photosphere: 0.9 log of abundance
  • Oceanic crust: 3.7 ppm
  • Solar system: 0.243 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Flammable dust. Possible carcinogen. Compounds moderately toxic..

   Human daily limits
  • Lower:
  • Upper:

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YtTErbium Physical Properties

 Transitional Data

  • State: Solid
  • Density: 6.9654 g/cm3

 Molar enthalpy

  • Atomization: 152.80 kJ mol-1
  • Fusion: 9.20 kJ mol-1
  • Vaporization: 159 kJ mol-1

 Transition points

  • MelTing point: 1092.0 K
  • Boiling point: 1467.0 K
  • Critical temperature: 4420.0 K

 Molar properties

  • Atomic weight: 173.04 g/mole
  • Molar volume: 25.00 cm3 mol-1

 Crystal structure sequence

hexagonal-close-packed <270 K < face-centered-cubic < 1005 K < body-centered-cubic < melTing point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 59.87
    • Heat Capacity 26.74
  • State: gas
    • Enthalpy 152.3
    • Gibbs function 118.4
    • Entropy 173.126
    • Heat Capacity 20.786

 Miscellaneous physical

  • Electrical resistivity: 29.0 µ-ohms/cm
  • Debye temperature: 120.0 K
  • Thermal conductivity: 34.9 W / m / K
  • Coefficient of linear expansion: 25.2Coef. per K
  • Mass magnetic susceptibility: 1.81e-8
  • X-ray diffraction mass absorption coefficients:
    • CuK: 146 (µ/p)/cm2 g-1
    • MoK: 84.5 (µ/p)/cm2 g-1

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YtTErbium Chemical Properties

 Chemical basics:

  • Oxidation states: +2 +3
  • Molecular wt: 173.04 g/mole

 Radii

  • Covalent: 170 pm
  • Atomic: 193.3 pm
  • Van der Waals: pm

 Ions:

  • ion: +2 pm 102.0
  • ion: +3 pm 86.8

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 2.85
  • Clementi: 8.59
  • Froese-Fischer: 11.90

 Electronegativity

  • Pauling:
  • Allred-Rochow: 1.06

 Standard reactions

oxidation =>
Yb+3 + 3e- =>

reduction
Yb
potential
-2.27

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YtTErbium Nuclear Properties

Isotopes
Number of isotopes:
  • Known 16
  • Listed 9
Isotope range:
  • Known 164 - 177
  • Listed 168 - 176
Nuclide 168
  • % Occ.:Natural 0.13%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 169
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 32.0 days
    • Decay mode: E.C.,
    • Source:
  • Notes
Nuclide 170
  • % Occ.:Natural 3.05%
  • Mossbauer NRA: 13.5
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 171
  • % Occ.:Natural 14.30%
  • Mossbauer NRA: 10.7
  • Nuclear spin/Quantum no.: 1/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 171
  • % Occ.:Natural
  • Mossbauer NRA: 12.1
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 172
  • % Occ.:Natural 21.90%
  • Mossbauer NRA: 12.6
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 173
  • % Occ.:Natural 16.12%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 5/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 174
  • % Occ.:Natural 31.80%
  • Mossbauer NRA: 12.3
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 176
  • % Occ.:Natural 12.70%
  • Mossbauer NRA: 13.2 *
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Thermal neutron capture
  • Isotope Cross-section 37±3 barns
Nuclear magnetic resonance
Nuclide: 171
  • Absolute sensitivity: 7.81e-4 1H=1.0
  • Relative sensitivity: 5.46e-3 1H=1.0
  • Receptivity: 4.05 13C=1.0
  • Magnetogyric ratio: 4.718e7 rad / T / s
  • Quadropole moment: m2
  • Frequency: 17.613 MHz
  • Reference:

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YtTErbium Energy Properties

Electrons

  • Ground state electron configuration: [Xe] 4f14 6s2
  • Electron affinity: <=50 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 2464.49
  • Relative intensity 65
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 1.5 NA
  • Notes:
 Wave length 2671.98
  • Relative intensity 55
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 14 NA
  • Notes:
 Wave length 3289.37
  • Relative intensity 2600
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml) 0.04
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3464.36
  • Relative intensity 340
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.8 NA
  • Notes:
 Wave length 3694.19
  • Relative intensity 3200
  • Detection limits
    • Arc (ug/g) 0.5
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3987.98
  • Relative intensity 1900
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.02 OAn
    • Atomic absorption (ug/ml) 0.3 NA
  • Notes:
 Wave length 5556.48
  • Relative intensity 140
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.2 OH; 0.06 OAn
    • Atomic absorption (ug/ml)
  • Notes:

 Ionization energies

Ionization level
Yb -> Yb+
Yb+ -> Yb+2
Ionization potential
603.4
1176

 Atomic energy levels

Orbital
ns

(n-2)f
Energy
0.8270

2.5609

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