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Interactive Demos
 68

Er

Erbium

Erbium General Information
 Categories
  • Class: Heavy Lanthinides
  • Period: 6
  • IUPAC group: 3
  • Traditional: IIIa
History
  • Discovered in: 1843 by Mosander
  • Origin of name: Ytterby, a town in Sweden
  • Historical or alternate name:
Common natural occurrences

Gadolinite

Description

Silvery grey metal; reacts slowly with water. Dissolves in acids.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 0.374 ppm
  • Sea water: 2e-7 ppm
  • Metallic meteorite: 0.160 ppm
  • ConTinental crust: 2.2 ppm
  • Solar photosphere: 0.76 log of abundance
  • Oceanic crust: 3.7 ppm
  • Solar system: 0.253 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Metal ignites and burns readily. Compounds moderately toxic by ingestion..

   Human daily limits
  • Lower:
  • Upper:

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Erbium Physical Properties

 Transitional Data

  • State: Solid
  • Density: 9.006 g/cm3

 Molar enthalpy

  • Atomization: 318.32 kJ mol-1
  • Fusion: 17.2 kJ mol-1
  • Vaporization: 280 kJ mol-1

 Transition points

  • MelTing point: 1802.0 K
  • Boiling point: 3136.0 K
  • Critical temperature: 7250.0 K

 Molar properties

  • Atomic weight: 167.26 g/mole
  • Molar volume: 18.565 cm3 mol-1

 Crystal structure sequence

hexagonal-close-packed <1190 K < body-centered-cubic < melTing point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 73.18
    • Heat Capacity 28.12
  • State: gas
    • Enthalpy 317.1
    • Gibbs function 280.7
    • Entropy 195.59
    • Heat Capacity 20.79

 Miscellaneous physical

  • Electrical resistivity: 107.0 µ-ohms/cm
  • Debye temperature: K
  • Thermal conductivity: 14.3 W / m / K
  • Coefficient of linear expansion: 9.4Coef. per K
  • Mass magnetic susceptibility: 3.33e-6
  • X-ray diffraction mass absorption coefficients:
    • CuK: 134 (µ/p)/cm2 g-1
    • MoK: 77.3 (µ/p)/cm2 g-1

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Erbium Chemical Properties

 Chemical basics:

  • Oxidation states: +3
  • Molecular wt: 167.26 g/mole

 Radii

  • Covalent: 157 pm
  • Atomic: 176.1 pm
  • Van der Waals: pm

 Ions:

  • ion: +3 pm 89.0

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 2.85
  • Clementi: 8.48
  • Froese-Fischer: 11.70

 Electronegativity

  • Pauling:
  • Allred-Rochow: 1.11

 Standard reactions

oxidation =>
Er+3 + 3e- =>

reduction
Er
potential
-2.30

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Erbium Nuclear Properties

Isotopes
Number of isotopes:
  • Known 16
  • Listed 7
Isotope range:
  • Known 158 - 172
  • Listed 162 - 170
Nuclide 162
  • % Occ.:Natural 0.14%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 164
  • % Occ.:Natural 1.61%
  • Mossbauer NRA: 14.6 *
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 166
  • % Occ.:Natural 33.60%
  • Mossbauer NRA: 12.9
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 167
  • % Occ.:Natural 22.95%
  • Mossbauer NRA: 12.7
  • Nuclear spin/Quantum no.: 7/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 168
  • % Occ.:Natural 26.80%
  • Mossbauer NRA: 12.8
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 169
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 9.40 days
    • Decay mode: Beta-
    • Source:
  • Notes
Nuclide 170
  • % Occ.:Natural 14.90%
  • Mossbauer NRA: 12.7
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Thermal neutron capture
  • Isotope Cross-section 0.16±0.03 barns
Nuclear magnetic resonance
Nuclide: 167
  • Absolute sensitivity: 1.16e-4 1H=1.0
  • Relative sensitivity: 5.07e-4 1H=1.0
  • Receptivity: 0.665 13C=1.0
  • Magnetogyric ratio: -.7752e7 rad / T / s
  • Quadropole moment: 2.83e-28 m2
  • Frequency: 2.890 MHz
  • Reference:

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Erbium Energy Properties

Electrons

  • Ground state electron configuration: [Xe] 4f12 6s2
  • Electron affinity: <=50 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 3372.76
  • Relative intensity 750
  • Detection limits
    • Arc (ug/g) 5
    • Spark (ug/ml) 2
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3499.11
  • Relative intensity 650
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3692.64
  • Relative intensity 700
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3892.69
  • Relative intensity 340
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 3.7 NA
  • Notes:
 Wave length 3896.25
  • Relative intensity 420
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3906.34
  • Relative intensity 850
  • Detection limits
    • Arc (ug/g) 4
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 4007.97
  • Relative intensity 1100
  • Detection limits
    • Arc (ug/g) 60
    • Spark (ug/ml)
    • Flame emission (ug/ml) 2 OA
    • Atomic absorption (ug/ml) 0.9 NA
  • Notes:
 Wave length 4087.65
  • Relative intensity 280
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.9 NA; 6.4 AA
  • Notes:
 Wave length 4151.10
  • Relative intensity 550
  • Detection limits
    • Arc (ug/g) 300
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 1.3 NA
  • Notes:
 Wave length 5040.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.07 OAn
    • Atomic absorption (ug/ml)
  • Notes: ErO
 Wave length 5520.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.1 OAN; 2 OH
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 5650.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 3 OH
    • Atomic absorption (ug/ml)
  • Notes:

 Ionization energies

Ionization level
Er -> Er+
Er+ -> Er+2
Ionization potential
588.7
1151

 Atomic energy levels

Orbital
ns

(n-2)f
Energy
0.8133

2.4890

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