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Interactive Demos
 39

Y

Yttrium

Yttrium General Information
 Categories
  • Class: Transition Metals
  • Period: 5
  • IUPAC group: 3
  • Traditional: IIIa
History
  • Discovered in: 1843 by Mosander
  • Origin of name: Ytterby, village in Sweden
  • Historical or alternate name:
Common natural occurrences

Monazite sand, bastnasite & yttria

Description

Soft, silvery white metal. Exposed surfaces form oxide film. Easily combusTABLE, reacts with Oxygen in water to release Hydrogen.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 3.4 ppm
  • Sea water: 0.0003 ppm
  • Metallic meteorite: 1.50 ppm
  • Continental crust: 20.0 ppm
  • Solar photosphere: 2.10 log of abundance
  • Oceanic crust: 32.0 ppm
  • Solar system: 4.64 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Flammable dust. Compounds may be toxic. Possible carcinogen..

   Human daily limits
  • Lower:0.01
  • Upper:1.0

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Yttrium Physical Properties

 Transitional Data

  • State: Solid
  • Density: 4.4689 g/cm3

 Molar enthalpy

  • Atomization: 420.45 kJ mol-1
  • Fusion: 17.2 kJ mol-1
  • Vaporization: 367.4 kJ mol-1

 Transition points

  • Melting point: 1795.0 K
  • Boiling point: 3611.0 K
  • Critical temperature: 8950.0 K

 Molar properties

  • Atomic weight: 88.90585 g/mole
  • Molar volume: 20.017 cm3 mol-1

 Crystal structure sequence

hexagonal-close-packed <1733 K < body-centered-cubic < melting point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 44.43
    • Heat Capacity 26.53
  • State: gas
    • Enthalpy 421.3
    • Gibbs function 381.1
    • Entropy 1179.48
    • Heat Capacity 25.86

 Miscellaneous physical

  • Electrical resistivity: 57.0 µ-ohms/cm
  • Debye temperature: 280.0 K
  • Thermal conductivity: 17.2 W / m / K
  • Coefficient of linear expansion: 11.3Coef. per K
  • Mass magnetic susceptibility: 2.70e-8
  • X-ray diffraction mass absorption coefficients:
    • CuK: 134 (µ/p)/cm2 g-1
    • MoK: 100 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Yttrium Chemical Properties

 Chemical basics:

  • Oxidation states: +3
  • Molecular wt: 88.90585 g/mole

 Radii

  • Covalent: 162 pm
  • Atomic: 182.0 pm
  • Van der Waals: pm

 Ions:

  • ion: +3 pm 90.0

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 3.00
  • Clementi: 6.26
  • Froese-Fischer: 8.72

 Electronegativity

  • Pauling: 1.2
  • Allred-Rochow: 1.11

 Standard reactions

oxidation =>
Y+3 + 3e- =>

reduction
Y
potential
-2.37

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Yttrium Nuclear Properties

Isotopes
Number of isotopes:
  • Known 21
  • Listed 3
Isotope range:
  • Known 82 - 96
  • Listed 88 - 91
Nuclide 88
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 107.0 days
    • Decay mode: E.C., Beta+
    • Source: reactor
  • Notes
Nuclide 89
  • % Occ.:Natural 100.0%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 1/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 91
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 58.5 days
    • Decay mode: Beta-
    • Source: reactor
  • Notes
Thermal neutron capture
  • Isotope Cross-section 1.3±0.1 barns
Nuclear magnetic resonance
Nuclide: 89
  • Absolute sensitivity: 1.18e-4 1H=1.0
  • Relative sensitivity: 1.18e-4 1H=1.0
  • Receptivity: 0.668 13C=1.0
  • Magnetogyric ratio: -1.3108e7 rad / T / s
  • Quadropole moment: m2
  • Frequency: 4.899 MHz
  • Reference: Y(NO3)3

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Yttrium Energy Properties

Electrons

  • Ground state electron configuration: [Kr] 4d1 5s2
  • Electron affinity: -39 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 3242.28
  • Relative intensity 800
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml) 0.2
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 3710.30
  • Relative intensity 1500
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml) 0.1
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 4077.38
  • Relative intensity 950
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 5.7 NA
  • Notes:
 Wave length 4102.38
  • Relative intensity 1000
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 3 OAn
    • Atomic absorption (ug/ml) 5 NA
  • Notes:
 Wave length 4128.31
  • Relative intensity 900
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 5.4 NA
  • Notes:
 Wave length 4142.85
  • Relative intensity 750
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 11 NA
  • Notes:
 Wave length 4374.94
  • Relative intensity 1200
  • Detection limits
    • Arc (ug/g) 1
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 4280.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.1 OAn
    • Atomic absorption (ug/ml)
  • Notes: YO
 Wave length 5980.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.02 OAn
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 6140.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.02 OAn
    • Atomic absorption (ug/ml)
  • Notes:

 Ionization energies

Ionization level
Y -> Y+
Y+ -> Y+2
Ionization potential
616
1181

 Atomic energy levels

Orbital
ns
(n-1)d
(n-1)p
Energy
0.8870
0.8911
5.2162

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