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Interactive Demos
 38

Sr

Strontium

Strontium General Information
 Categories
  • Class: Alkalines
  • Period: 5
  • IUPAC group: 2
  • Traditional: IIa
History
  • Discovered in: 1808 by Davy
  • Origin of name: Strontian, town in Scotland
  • Historical or alternate name:
Common natural occurrences

Celestite (SrSO4) & strontianite (SrCO3)

Description

Soft, silvery white metal. CombusTABLE in air, will react with water. Exposed surfaces form protective oxide film.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 17.8 ppm
  • Sea water: 8 ppm
  • Metallic meteorite: 7.91 ppm
  • Continental crust: 260.0 ppm
  • Solar photosphere: 2.90 log of abundance
  • Oceanic crust: 130.0 ppm
  • Solar system: 23.8 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Metal ignites and burns readily. Reacts with water and oxidants. Metal moderately toxic by ingestion and inhalation..

   Human daily limits
  • Lower:1.0
  • Upper:100.0

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Strontium Physical Properties

 Transitional Data

  • State: Solid
  • Density: 2.6 g/cm3

 Molar enthalpy

  • Atomization: 164.4 kJ mol-1
  • Fusion: 9.16 kJ mol-1
  • Vaporization: 154.4 kJ mol-1

 Transition points

  • Melting point: 1042.0 K
  • Boiling point: 1657.0 K
  • Critical temperature: 3059.0 K

 Molar properties

  • Atomic weight: 87.62 g/mole
  • Molar volume: 34.07 cm3 mol-1

 Crystal structure sequence

face-centered-cubic <486 K < hexagonal-close-packed < 878 K < body-centered-cubic < melting point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 52.3
    • Heat Capacity 26.4
  • State: gas
    • Enthalpy 164.4
    • Gibbs function 130.9
    • Entropy 164.62
    • Heat Capacity 20.786

 Miscellaneous physical

  • Electrical resistivity: 23.0 µ-ohms/cm
  • Debye temperature: 147.0 K
  • Thermal conductivity: 49.0 W / m / K
  • Coefficient of linear expansion: 22.5Coef. per K
  • Mass magnetic susceptibility: 1.32e-8
  • X-ray diffraction mass absorption coefficients:
    • CuK: 125 (µ/p)/cm2 g-1
    • MoK: 95.0 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Strontium Chemical Properties

 Chemical basics:

  • Oxidation states: +2
  • Molecular wt: 87.62 g/mole

 Radii

  • Covalent: 192 pm
  • Atomic: 215.0 pm
  • Van der Waals: pm

 Ions:

  • ion: +2 pm 118.0

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 2.85
  • Clementi: 6.07
  • Froese-Fischer: 8.09

 Electronegativity

  • Pauling: 1.0
  • Allred-Rochow: 0.99

 Standard reactions

oxidation =>
Sr+2 + 2e- =>

reduction
Sr
potential
-2.89

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Strontium Nuclear Properties

Isotopes
Number of isotopes:
  • Known 18
  • Listed 8
Isotope range:
  • Known 80 - 95
  • Listed 82 - 90
Nuclide 82
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 25.5 days
    • Decay mode: E.C.,
    • Source: reactor
  • Notes
Nuclide 84
  • % Occ.:Natural 0.56%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 85
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 64.9 days
    • Decay mode: E.C.,
    • Source: reactor
  • Notes med
Nuclide 86
  • % Occ.:Natural 9.86%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 87
  • % Occ.:Natural 7.00%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 9/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 88
  • % Occ.:Natural 82.58%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 89
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 50.5 days
    • Decay mode: Beta-
    • Source: reactor
  • Notes
Nuclide 90
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 28.5 years
    • Decay mode: Beta-
    • Source: reactor
  • Notes med
Thermal neutron capture
  • Isotope Cross-section 1.21±0.06 barns
Nuclear magnetic resonance
Nuclide: 87
  • Absolute sensitivity: 1.88e-4 1H=1.0
  • Relative sensitivity: 2.69e-3 1H=1.0
  • Receptivity: 1.07 13C=1.0
  • Magnetogyric ratio: -1.1593e7 rad / T / s
  • Quadropole moment: 0.36e-28 m2
  • Frequency: 4.333 MHz
  • Reference: Sr+2

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Strontium Energy Properties

Electrons

  • Ground state electron configuration: [Kr] 5s2
  • Electron affinity: -146 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 3464.46
  • Relative intensity 65
  • Detection limits
    • Arc (ug/g) 10
    • Spark (ug/ml)
    • Flame emission (ug/ml) 26 OAn
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 4077.71
  • Relative intensity 4600
  • Detection limits
    • Arc (ug/g) 0.1
    • Spark (ug/ml) 0.006
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 4607.33
  • Relative intensity 650
  • Detection limits
    • Arc (ug/g) 0.1
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.09 OH; 0.06 OA
    • Atomic absorption (ug/ml) 0.06 AA or NA
  • Notes:
 Wave length 6060.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.3 OH; 0.6 OA
    • Atomic absorption (ug/ml)
  • Notes: SrOH

 Ionization energies

Ionization level
Sr -> Sr+
Sr+ -> Sr+2
Ionization potential
549.5
1064.2

 Atomic energy levels

Orbital
ns
(n-1)p
(n-1)s
Energy
0.8026
4.4363
7.2056

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

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