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Interactive Demos
 27

Co

Cobalt

Cobalt General Information
 Categories
  • Class: Transition Metals
  • Period: 4
  • IUPAC group: 9
  • Traditional: VIII
History
  • Discovered in: 1735 by Brandt
  • Origin of name: German: Kobald, (a goblin or evil spirit)
  • Historical or alternate name:
Common natural occurrences

Cobaltite, smaltite, erythrite & nickel, silver, copper & Iron ores

Description

Silvery-blue, lustrous, hard metal. Surfaces sTABLE in air. Reacts over time with dilute acids.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 100.0 ppm
  • Sea water: 0.0005 ppm
  • Metallic meteorite: 509.0 ppm
  • Continental crust: 29.0 ppm
  • Solar photosphere: 4.90 log of abundance
  • Oceanic crust: 47.0 ppm
  • Solar system: 2250.0 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Compounds may be toxic..

   Human daily limits
  • Lower:0.01
  • Upper:1.0

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Cobalt Physical Properties

 Transitional Data

  • State: Solid
  • Density: 8.9 g/cm3

 Molar enthalpy

  • Atomization: 423.082 kJ mol-1
  • Fusion: 15.2 kJ mol-1
  • Vaporization: 382.4 kJ mol-1

 Transition points

  • Melting point: 1768.0 K
  • Boiling point: 3143.0 K
  • Critical temperature: 5400.0 K

 Molar properties

  • Atomic weight: 58.9332 g/mole
  • Molar volume: 6.712 cm3 mol-1

 Crystal structure sequence

hexagonal-close-packed <661 K < face-centered-cubic < melting point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 30.04
    • Heat Capacity 24.81
  • State: gas
    • Enthalpy 424.7
    • Gibbs function 380.3
    • Entropy 179.515
    • Heat Capacity 23.020

 Miscellaneous physical

  • Electrical resistivity: 6.24 µ-ohms/cm
  • Debye temperature: 445.0 K
  • Thermal conductivity: 100.0 W / m / K
  • Coefficient of linear expansion: 13.1Coef. per K
  • Mass magnetic susceptibility: (ferro-magnetic)
  • X-ray diffraction mass absorption coefficients:
    • CuK: 313 (µ/p)/cm2 g-1
    • MoK: 42.5 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Cobalt Chemical Properties

 Chemical basics:

  • Oxidation states: +2 +3 +4
  • Molecular wt: 58.9332 g/mole

 Radii

  • Covalent: 116 pm
  • Atomic: 125.0 pm
  • Van der Waals: pm

 Ions:

  • ion: +2 pm 74.5
  • ion: +3 pm 61.0
  • ion: +4 pm 53.0

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 3.90
  • Clementi: 5.58
  • Froese-Fischer: 7.63

 Electronegativity

  • Pauling: 1.9
  • Allred-Rochow: 1.70

 Standard reactions

oxidation =>
Co+3 + e- =>
Co(OH)3 + e- =>
Co(NH3)+3 + e- =>
Co+2 + 2e- =>

reduction
Co+2
Co(OH)2 + OH-
Co(NH3)6+2
Co
potential
1.82
0.17
0.1
-0.28

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Cobalt Nuclear Properties

Isotopes
Number of isotopes:
  • Known 14
  • Listed 5
Isotope range:
  • Known 54 - 63
  • Listed 56 - 60
Nuclide 56
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 78.80 days
    • Decay mode: E.C., Beta+
    • Source:
  • Notes
Nuclide 57
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 271.00 days
    • Decay mode: E.C.,
    • Source:
  • Notes med
Nuclide 58
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 70.80 days
    • Decay mode: E.C., Beta+
    • Source:
  • Notes med
Nuclide 59
  • % Occ.:Natural 100.0%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 7/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 60
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 5/0
  • Radioisotopes:
    • Half-life: 5.27 years
    • Decay mode: Beta-
    • Source:
  • Notes med
Thermal neutron capture
  • Isotope Cross-section 37.5±0.2 barns
Nuclear magnetic resonance
Nuclide: 59
  • Absolute sensitivity: 0.28 1H=1.0
  • Relative sensitivity: 0.28 1H=1.0
  • Receptivity: 1570 13C=1.0
  • Magnetogyric ratio: 6.3472e7 rad / T / s
  • Quadropole moment: 0.40e-28 m2
  • Frequency: 23.614 MHz
  • Reference: K3Co(CN)6

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Cobalt Energy Properties

Electrons

  • Ground state electron configuration: [Ar] 3d7 4s2
  • Electron affinity: 102 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 2174.60
  • Relative intensity 2
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 3.5 AA (5-100)
  • Notes:
 Wave length 2286.16
  • Relative intensity 26
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml) 0.5
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 2309.02
  • Relative intensity 24
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 7 AA (10-500)
  • Notes:
 Wave length 2363.79
  • Relative intensity 30
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml) 0.5
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 2407.25
  • Relative intensity 140
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.22 AA (1-50)
  • Notes:
 Wave length 2424.93
  • Relative intensity 130
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 1.7 OAr
    • Atomic absorption (ug/ml) 0.2 AA (1-50)
  • Notes:
 Wave length 2435.83
  • Relative intensity 25
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 1.4 AA (5-100)
  • Notes:
 Wave length 2521.36
  • Relative intensity 180
  • Detection limits
    • Arc (ug/g) 3
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.8 AA (3-100)
  • Notes:
 Wave length 2987.16
  • Relative intensity 36
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 12 AA (50-1000)
  • Notes:
 Wave length 2989.59
  • Relative intensity 36
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 12 AA (50-1000)
  • Notes:
 Wave length 3044.00
  • Relative intensity 160
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 2.3 AA (5-500)
  • Notes:
 Wave length 3405.12
  • Relative intensity 700
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 6.2 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3412.63
  • Relative intensity 140
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 5.2 OA
    • Atomic absorption (ug/ml) 0.7 AA (3-100)
  • Notes:
 Wave length 3431.58
  • Relative intensity 160
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 10 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3443.64
  • Relative intensity 550
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 14 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3453.50
  • Relative intensity 1300
  • Detection limits
    • Arc (ug/g) 1
    • Spark (ug/ml) 2.0
    • Flame emission (ug/ml) 3.4 OA; 0.8 OAn
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3465.80
  • Relative intensity 320
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 6.4 OA
    • Atomic absorption (ug/ml) 6 AA (10-1000)
  • Notes:
 Wave length 3474.02
  • Relative intensity 500
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 8 OA
    • Atomic absorption (ug/ml) 10 AA (50-1000)
  • Notes:
 Wave length 3506.32
  • Relative intensity 440
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 6 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3512.48
  • Relative intensity 240
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 10 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3526.85
  • Relative intensity 400
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 4 OA
    • Atomic absorption (ug/ml) 4 AA (10-1000)
  • Notes:
 Wave length 3873.12
  • Relative intensity 240
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 6 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 4121.32
  • Relative intensity 190
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 15 OA
    • Atomic absorption (ug/ml)
  • Notes:

 Ionization energies

Ionization level
Co -> Co+
Co+ -> Co+2
Ionization potential
760.0
1646

 Atomic energy levels

Orbital
ns
(n-1)d
(n-1)p
Energy
1.2310
2.2703
11.597

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

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