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Iron General Information
 Categories
  • Class: Transition Metals
  • Period: 4
  • IUPAC group: 8
  • Traditional: VIII
History
  • Discovered in: ~ 2500 BC by
  • Origin of name: Latin: ferrum
  • Historical or alternate name: Ferrum
Common natural occurrences

Hematite, magnetite (black sands) & taconite

Description

Lustrous, silvery, soft (when pure), metal. Exposed surfaces form red-brown oxides. Forms very strong alloys (steel). Ferromagnetic.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 62200.0 ppm
  • Sea water: 0.01 ppm
  • Metallic meteorite: 185100.0 ppm
  • Continental crust: 70700.0 ppm
  • Solar photosphere: 7.50 log of abundance
  • Oceanic crust: 81600.0 ppm
  • Solar system: 9.0E+5 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Metal dust flammable. Compounds may be toxic. Possible carcinogen..

   Human daily limits
  • Lower:1.0
  • Upper:100.0

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Iron Physical Properties

 Transitional Data

  • State: Solid
  • Density: 7.86 g/cm3

 Molar enthalpy

  • Atomization: 413.96 kJ mol-1
  • Fusion: 14.9 kJ mol-1
  • Vaporization: 340.2 kJ mol-1

 Transition points

  • Melting point: 1808.0 K
  • Boiling point: 3023.0 K
  • Critical temperature: 5966.0 K

 Molar properties

  • Atomic weight: 55.847 g/mole
  • Molar volume: 7.137 cm3 mol-1

 Crystal structure sequence

body-centered-cubic <1183 K < face-centered-cubic < 1663 K < body-centered-cubic < melting point

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 27.28
    • Heat Capacity 25.10
  • State: gas
    • Enthalpy 416.3
    • Gibbs function 370.7
    • Entropy 180.490
    • Heat Capacity 25.677

 Miscellaneous physical

  • Electrical resistivity: 9.71 µ-ohms/cm
  • Debye temperature: 470.0 K
  • Thermal conductivity: 80.2 W / m / K
  • Coefficient of linear expansion: 11.9Coef. per K
  • Mass magnetic susceptibility: (ferro-magnetic)
  • X-ray diffraction mass absorption coefficients:
    • CuK: 308 (µ/p)/cm2 g-1
    • MoK: 38.5 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Iron Chemical Properties

 Chemical basics:

  • Oxidation states: +2 +3 +4
  • Molecular wt: 55.847 g/mole

 Radii

  • Covalent: 116.5 pm
  • Atomic: 126.0 pm
  • Van der Waals: pm

 Ions:

  • ion: +2 pm 78.0
  • ion: +3 pm 64.5
  • ion: +4 pm 58.5

 Covalent bonds

Bond:
Radius
Energy

 Effective nuclear charge

  • Slater: 3.75
  • Clementi: 5.43
  • Froese-Fischer: 7.40

 Electronegativity

  • Pauling: 1.8
  • Allred-Rochow: 1.64

 Standard reactions

oxidation =>
FeO4-2 + 8H+ + 3e- =>
Fe+3 + e- =>
Fe(CN)6-3 + e- =>
Fe+3 + 3e- =>
Fe+2 + 2e- =>
Fe(OH)3 + e- =>

reduction
Fe+3 + 4H2O
Fe+2
Fe(CN)6-4
Fe
Fe
Fe(OH)2 + OH-
potential
1.9
0.771
0.356
-0.04
-0.44
-0.56

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Iron Nuclear Properties

Isotopes
Number of isotopes:
  • Known 10
  • Listed 8
Isotope range:
  • Known 52 - 61
  • Listed 54 - 60
Nuclide 54
  • % Occ.:Natural 5.80%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 55
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 3/2
  • Radioisotopes:
    • Half-life: 2.7 years
    • Decay mode: E.C.,
    • Source:
  • Notes med
Nuclide 56
  • % Occ.:Natural 91.72%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 57
  • % Occ.:Natural 2.20%
  • Mossbauer NRA: 2.307 *
  • Nuclear spin/Quantum no.: 1/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 57
  • % Occ.:Natural
  • Mossbauer NRA: 21.870
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 58
  • % Occ.:Natural 0.28%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Nuclide 59
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 45.1 days
    • Decay mode: Beta-
    • Source:
  • Notes med
Nuclide 60
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.:
  • Radioisotopes:
    • Half-life: 0.1 E6 years
    • Decay mode: Beta-
    • Source:
  • Notes
Thermal neutron capture
  • Isotope Cross-section 2.56±0.05 barns
Nuclear magnetic resonance
Nuclide: 57
  • Absolute sensitivity: 7.38e-7 1H=1.0
  • Relative sensitivity: 3.37e-5 1H=1.0
  • Receptivity: 4.2e-3 13C=1.0
  • Magnetogyric ratio: 0.8661e7 rad / T / s
  • Quadropole moment: m2
  • Frequency: 3.231 MHz
  • Reference: Fe(CO)5

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Iron Energy Properties

Electrons

  • Ground state electron configuration: [Ar] 3d6 4s2
  • Electron affinity: 44 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 2166.77
  • Relative intensity 15
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.7 AAr (1-100)
  • Notes:
 Wave length 2382.04
  • Relative intensity 60
  • Detection limits
    • Arc (ug/g) 0.5
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 2395.62
  • Relative intensity 60
  • Detection limits
    • Arc (ug/g) 0.5
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 2483.27
  • Relative intensity 280
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.15 AAr (1-30)
  • Notes:
 Wave length 2484.19
  • Relative intensity 90
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.18 AAr (1-50)
  • Notes:
 Wave length 2487.97
  • Relative intensity 4
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.3 AAr (1-30)
  • Notes:
 Wave length 2489.75
  • Relative intensity 180
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.6 AAr (3-50)
  • Notes: d
 Wave length 2490.64
  • Relative intensity 180
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.6 AAr (3-50)
  • Notes: D
 Wave length 2510.83
  • Relative intensity 90
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 1.6 AAr (5-500)
  • Notes:
 Wave length 2524.39
  • Relative intensity 50
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 4 AAr (10-100)
  • Notes:
 Wave length 2527.43
  • Relative intensity 140
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.8 AAr (5-100)
  • Notes:
 Wave length 2599.40
  • Relative intensity 200
  • Detection limits
    • Arc (ug/g) 0.2
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml)
  • Notes: II
 Wave length 2719.02
  • Relative intensity 260
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 0.5 AAr (1-100)
  • Notes:
 Wave length 2744.07
  • Relative intensity 30
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 4 AAr (30-400)
  • Notes:
 Wave length 3020.64
  • Relative intensity 280
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.2 OAn
    • Atomic absorption (ug/ml) 0.5 AAr (5-50)
  • Notes:
 Wave length 3440.61
  • Relative intensity 400
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.44 OAn
    • Atomic absorption (ug/ml) 2.4 AAr (10-500)
  • Notes:
 Wave length 3581.20
  • Relative intensity 600
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.8 OAn; 15 OA
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3719.95
  • Relative intensity 600
  • Detection limits
    • Arc (ug/g) 0.2
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.12 OAn; 3 OA
    • Atomic absorption (ug/ml) 1 AAr (5-100)
  • Notes:
 Wave length 3734.87
  • Relative intensity 700
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.16 OAn
    • Atomic absorption (ug/ml)
  • Notes:
 Wave length 3748.26
  • Relative intensity 140
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.23 OAn
    • Atomic absorption (ug/ml) 4 AAr (30-1000)
  • Notes:
 Wave length 3859.91
  • Relative intensity 420
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.14 OAN; 3 OA
    • Atomic absorption (ug/ml) 2.1 AAr (30-500)
  • Notes:
 Wave length 3886.28
  • Relative intensity 180
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 6 AAr (50-1000)
  • Notes:
 Wave length 3920.26
  • Relative intensity 36
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 3.5 OAn
    • Atomic absorption (ug/ml) 40 AAr (300-1000)
  • Notes:
 Wave length 3927.92
  • Relative intensity 70
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 10 OA
    • Atomic absorption (ug/ml) 24 AAr (100-1000)
  • Notes:

 Ionization energies

Ionization level
Fe -> Fe+
Fe+ -> Fe+2
Ionization potential
759.3
1561

 Atomic energy levels

Orbital
ns
(n-1)d
(n-1)p
Energy
1.1882
2.0981
10.662

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

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