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Interactive Demos
 13

Al

Aluminum

Aluminum General Information
 Categories
  • Class: Metals
  • Period: 3
  • IUPAC group: 13
  • Traditional: IIIb
History
  • Discovered in: 1825 by Oersted, also Wohler, 1827
  • Origin of name: Latin: alumen, alum also Aluminium
  • Historical or alternate name:
Common natural occurrences

Alum, bauxite, feldspars, granite & other common minerals

Description

Hard, silvery white metal. Exposed surfaces quickly form protective oxide coating.

Abundances
  • Atmosphere: ~0.0 ppm
  • Primitive mantle: 19300.0 ppm
  • Sea water: 0.01 ppm
  • Metallic meteorite: 8620.0 ppm
  • Continental crust: 84100.0 ppm
  • Solar photosphere: 6.52 log of abundance
  • Oceanic crust: 84700.0 ppm
  • Solar system: 84900.0 relative to Si=1.0e6
Hazards and Tolerances

   Hazards

Metal reacts violently with oxidants..

   Human daily limits

  • Lower:1.0
  • Upper:100.0

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Aluminum Physical Properties

 Transitional Data

  • State: Solid
  • Density: 2.702 g/cm3

 Molar enthalpy

  • Atomization: 324.01 kJ mol-1
  • Fusion: 10.67 kJ mol-1
  • Vaporization: 290.8 kJ mol-1

 Transition points

  • Melting point: 933.25 K
  • Boiling point: 2793.0 K
  • Critical temperature: 8550.0 K

 Molar properties

  • Atomic weight: 26.981539 g/mole
  • Molar volume: 10.061 cm3 mol-1

 Crystal structure sequence

face-centered-cubic

 Thermodynamics

  • State: solid
    • Enthalpy 0
    • Gibbs function 0
    • Entropy 28.33
    • Heat Capacity 24.35
  • State: gas
    • Enthalpy 326.4
    • Gibbs function 285.7
    • Entropy 165.54
    • Heat Capacity 21.38

 Miscellaneous physical

  • Electrical resistivity: 2.650 µ-ohms/cm
  • Debye temperature: 428.0 K
  • Thermal conductivity: 237.0 W / m / K
  • Coefficient of linear expansion: 23.2Coef. per K
  • Mass magnetic susceptibility: 7.7e-9
  • X-ray diffraction mass absorption coefficients:
    • CuK: 48.6 (µ/p)/cm2 g-1
    • MoK: 5.16 (µ/p)/cm2 g-1

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Aluminum Chemical Properties

 Chemical basics:

  • Oxidation states: +3
  • Molecular wt: 26.981539 g/mole

 Radii

  • Covalent: 125 pm
  • Atomic: 143.0 pm
  • Van der Waals: 205 pm

 Ions:

  • ion: +3 pm 53.5

 Covalent bonds

Bond:
Al-H
Al-C
Al-O
Al-F
Al-Cl
Al-Al
Radius
170
224
162
163
206
286
Energy
285
225
585
665
498
200

 Effective nuclear charge

  • Slater: 3.50
  • Clementi: 4.07
  • Froese-Fischer: 3.64

 Electronegativity

  • Pauling: 1.61
  • Allred-Rochow: 1.47

 Standard reactions

oxidation =>
Al+3 + 3e- =>
Al(OH)3 + 3e- =>

reduction
Al
Al + 3OH-
potential
-1.67
-2.31

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Aluminum Nuclear Properties

Isotopes
Number of isotopes:
  • Known 8
  • Listed 2
Isotope range:
  • Known 24 - 30
  • Listed 26 - 27
Nuclide 26
  • % Occ.:Natural
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 5/0
  • Radioisotopes:
    • Half-life: 0.716 E6 years
    • Decay mode: Beta+
    • Source: Cosmic irradiation.
  • Notes date
Nuclide 27
  • % Occ.:Natural 100.0%
  • Mossbauer NRA:
  • Nuclear spin/Quantum no.: 5/2
  • Radioisotopes:
    • Half-life:
    • Decay mode:
    • Source:
  • Notes
Thermal neutron capture
  • Isotope Cross-section 0.232 barns
Nuclear magnetic resonance  
Nuclide: 27
  • Absolute sensitivity: 0.21 1H=1.0
  • Relative sensitivity: 0.21 1H=1.0
  • Receptivity: 1.17e3 13C=1.0
  • Magnetogyric ratio: 6.9704e7 rad / T / s
  • Quadropole moment: 0.4193e-28 m2
  • Frequency: 26.057 MHz
  • Reference: Al(H2O)6+3
 

Return to Top   Element Properties: General - Physical - Chemical - Nuclear - Energy

Aluminum Energy Properties

Electrons

  • Ground state electron configuration: [Ne] 3s2 3p1
  • Electron affinity: 44 kJ mol-1
  • Filling orbitals:

Spectral lines

 Wave length 2269.09
  • Relative intensity 2
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 9 NAr (10-1000)
  • Notes:
 Wave length 2367.06
  • Relative intensity 18
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 8 NAr (10-1000)
  • Notes:
 Wave length 2373.13
  • Relative intensity 36
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 5 NAr (100-1000)
  • Notes: d
 Wave length 2567.99
  • Relative intensity 24
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 16 NAr (100-1000)
  • Notes:
 Wave length 2575.10
  • Relative intensity 48
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 11 NAr (100-1000)
  • Notes: D
 Wave length 3082.16
  • Relative intensity 320
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 4 NAr (10-500)
  • Notes:
 Wave length 3092.71
  • Relative intensity 650
  • Detection limits
    • Arc (ug/g) 1.0
    • Spark (ug/ml)
    • Flame emission (ug/ml)
    • Atomic absorption (ug/ml) 2.2 NAr (5-100)
  • Notes: D
 Wave length 3944.03
  • Relative intensity 450
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.3 OAn
    • Atomic absorption (ug/ml) 5 NAr (10-200)
  • Notes:
 Wave length 3961.53
  • Relative intensity 900
  • Detection limits
    • Arc (ug/g) 1.0
    • Spark (ug/ml) 0.3
    • Flame emission (ug/ml) 0.5 OAn
    • Atomic absorption (ug/ml) 3 NAr (10-200)
  • Notes:
 Wave length 4842.0
  • Relative intensity
  • Detection limits
    • Arc (ug/g)
    • Spark (ug/ml)
    • Flame emission (ug/ml) 0.5 OAn
    • Atomic absorption (ug/ml)
  • Notes: AlO

 Ionization energies

Ionization level
Al -> Al+
Al+ -> Al+2
Ionization potential
577.4
1816.6

 Atomic energy levels

Orbital
np
ns
Energy
0.7808
1.6229

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